A team of Boston College researchers has demonstrated an unprecedented catalytic approach that enables concurrent control of multiple convergences and selectivities in intermolecular amination of ...
In recent research 4 we have observed a case of true electromerism in a pair of organic radical cations containing two allylic moieties. The two electromers distinguish themselves by the nature of ...
A more reasonable scenario postulated by Pryor and Porter, involves an Epoxy Hydroperoxide Fragmentation (2). The key cyclization of an allylic alkoxyl radical to a carbon-centered allylic radical had ...
Herein, the authors report a Ni(ІІ)-catalyzed asymmetric alkenylation and arylation of aryl ketones with organoborons under air via a 1,5-metalate shift to obtain chiral tertiary allylic ...